A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation

Bao Yong Zhu; Tao Zhang; Chun Hui Li; Jian Wei Cao; Zhu Qing Zhang; Wei Qi; Guang Yin Wang; Zhi Hui Rong; Yu Wang; Kai Jie Chen

doi:10.1021/acs.inorgchem.2c00004

A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C₂H₂/CO₂Separation

Bao Yong Zhu
, Tao Zhang
, Chun Hui Li
, Jian Wei Cao
, Zhu Qing Zhang
, Wei Qi
, Guang Yin Wang
, Zhi Hui Rong
, Yu Wang
, Kai Jie Chen

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc^2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni₃(μ₃-OH)(tdc)₃(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C₂H₂over CO₂in an efficient manner.

Original language	English
Pages (from-to)	4555-4560
Number of pages	6
Journal	Inorganic Chemistry
Volume	61
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.2c00004
State	Published - 21 Mar 2022

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10.1021/acs.inorgchem.2c00004

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title = "A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation",

abstract = "Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.",

author = "Zhu, \{Bao Yong\} and Tao Zhang and Li, \{Chun Hui\} and Cao, \{Jian Wei\} and Zhang, \{Zhu Qing\} and Wei Qi and Wang, \{Guang Yin\} and Rong, \{Zhi Hui\} and Yu Wang and Chen, \{Kai Jie\}",

year = "2022",

month = mar,

day = "21",

doi = "10.1021/acs.inorgchem.2c00004",

language = "英语",

volume = "61",

pages = "4555--4560",

journal = "Inorganic Chemistry",

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TY - JOUR

T1 - A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation

AU - Zhu, Bao Yong

AU - Zhang, Tao

AU - Li, Chun Hui

AU - Cao, Jian Wei

AU - Zhang, Zhu Qing

AU - Qi, Wei

AU - Wang, Guang Yin

AU - Rong, Zhi Hui

AU - Wang, Yu

AU - Chen, Kai Jie

PY - 2022/3/21

Y1 - 2022/3/21

N2 - Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.

AB - Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.

UR - https://www.scopus.com/pages/publications/85126547440

U2 - 10.1021/acs.inorgchem.2c00004

DO - 10.1021/acs.inorgchem.2c00004

M3 - 文章

C2 - 35257588

AN - SCOPUS:85126547440

SN - 0020-1669

VL - 61

SP - 4555

EP - 4560

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C₂H₂/CO₂Separation

Abstract

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