A 2D Metal-Organic Framework Based on 9-(Pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic Acid: Synthesis, Structure and Properties

Xinhui Zhou; Yali Zhu; Liang Li; Wei Huang

doi:10.1002/cjoc.201700310

A 2D Metal-Organic Framework Based on 9-(Pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic Acid: Synthesis, Structure and Properties

Xinhui Zhou, Yali Zhu, Liang Li, Wei Huang

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A metal-organic framework (MOF) formulated as [Cd₂(μ₃-L)₂(DMF)₄]•H₂O (CdL) [H₂L=9-(pyridin-4-yl)- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CdL features the layered 2D framework with L² ⁻ ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CdL has a similar emission spectrum curve to the free H₂L ligand that indicates the emission of compound CdL should be originated from the coordinated L² ⁻ ligands.

Original language	English
Pages (from-to)	1869-1874
Number of pages	6
Journal	Chinese Journal of Chemistry
Volume	35
Issue number	12
DOIs	https://doi.org/10.1002/cjoc.201700310
State	Published - 1 Dec 2017
Externally published	Yes

Keywords

9-(pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic acid
cadmium complex
crystal structure
metal-organic frameworks

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10.1002/cjoc.201700310

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title = "A 2D Metal-Organic Framework Based on 9-(Pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic Acid: Synthesis, Structure and Properties",

abstract = "A metal-organic framework (MOF) formulated as [Cd2(μ3-L)2(DMF)4]•H2O (CdL) [H2L=9-(pyridin-4-yl)- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CdL features the layered 2D framework with L2 − ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CdL has a similar emission spectrum curve to the free H2L ligand that indicates the emission of compound CdL should be originated from the coordinated L2 − ligands.",

keywords = "9-(pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic acid, cadmium complex, crystal structure, metal-organic frameworks",

author = "Xinhui Zhou and Yali Zhu and Liang Li and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2017 SIOC, CAS, Shanghai, & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2017",

month = dec,

day = "1",

doi = "10.1002/cjoc.201700310",

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volume = "35",

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journal = "Chinese Journal of Chemistry",

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TY - JOUR

T1 - A 2D Metal-Organic Framework Based on 9-(Pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic Acid

T2 - Synthesis, Structure and Properties

AU - Zhou, Xinhui

AU - Zhu, Yali

AU - Li, Liang

AU - Huang, Wei

PY - 2017/12/1

Y1 - 2017/12/1

N2 - A metal-organic framework (MOF) formulated as [Cd2(μ3-L)2(DMF)4]•H2O (CdL) [H2L=9-(pyridin-4-yl)- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CdL features the layered 2D framework with L2 − ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CdL has a similar emission spectrum curve to the free H2L ligand that indicates the emission of compound CdL should be originated from the coordinated L2 − ligands.

AB - A metal-organic framework (MOF) formulated as [Cd2(μ3-L)2(DMF)4]•H2O (CdL) [H2L=9-(pyridin-4-yl)- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CdL features the layered 2D framework with L2 − ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CdL has a similar emission spectrum curve to the free H2L ligand that indicates the emission of compound CdL should be originated from the coordinated L2 − ligands.

KW - 9-(pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic acid

KW - cadmium complex

KW - crystal structure

KW - metal-organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=85026396438&partnerID=8YFLogxK

U2 - 10.1002/cjoc.201700310

DO - 10.1002/cjoc.201700310

M3 - 文章

AN - SCOPUS:85026396438

SN - 1001-604X

VL - 35

SP - 1869

EP - 1874

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 12

ER -

A 2D Metal-Organic Framework Based on 9-(Pyridin-4-yl)-9H-carbazole-3,6-dicarboxylic Acid: Synthesis, Structure and Properties

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Keywords

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