3,5-Dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine as an insensitive and thermostable energetic melt-castable material

Dangyue Yin; Boqian Yang; Hongyu Lv; Siwei Song; Yi Wang; Qinghua Zhang

doi:10.1039/d4ce01036a

3,5-Dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine as an insensitive and thermostable energetic melt-castable material

Dangyue Yin, Boqian Yang, Hongyu Lv, Siwei Song, Yi Wang, Qinghua Zhang

School of Astronautics

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A trifluoropropyl functionalized energetic compound, viz. 3,5-dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine (TFDNPA), was designed and synthesized, which exhibited potential for TNT replacement as an energetic melt-castable carrier in aluminized explosive formulation due to excellent thermal properties (T_m: 100 °C and T_d: 261 °C), good detonation performance (D: 7330 m s⁻¹ and P: 23.3 GPa), low impact sensitivity (IS: 35 J) and enhanced reaction activity with aluminium powders in melt-cast explosive formulations.

Original language	English
Pages (from-to)	8-12
Number of pages	5
Journal	CrystEngComm
Volume	27
Issue number	1
DOIs	https://doi.org/10.1039/d4ce01036a
State	Published - 18 Nov 2024

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abstract = "A trifluoropropyl functionalized energetic compound, viz. 3,5-dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine (TFDNPA), was designed and synthesized, which exhibited potential for TNT replacement as an energetic melt-castable carrier in aluminized explosive formulation due to excellent thermal properties (Tm: 100 °C and Td: 261 °C), good detonation performance (D: 7330 m s−1 and P: 23.3 GPa), low impact sensitivity (IS: 35 J) and enhanced reaction activity with aluminium powders in melt-cast explosive formulations.",

author = "Dangyue Yin and Boqian Yang and Hongyu Lv and Siwei Song and Yi Wang and Qinghua Zhang",

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T1 - 3,5-Dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine as an insensitive and thermostable energetic melt-castable material

AU - Yin, Dangyue

AU - Yang, Boqian

AU - Lv, Hongyu

AU - Song, Siwei

AU - Wang, Yi

AU - Zhang, Qinghua

PY - 2024/11/18

Y1 - 2024/11/18

N2 - A trifluoropropyl functionalized energetic compound, viz. 3,5-dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine (TFDNPA), was designed and synthesized, which exhibited potential for TNT replacement as an energetic melt-castable carrier in aluminized explosive formulation due to excellent thermal properties (Tm: 100 °C and Td: 261 °C), good detonation performance (D: 7330 m s−1 and P: 23.3 GPa), low impact sensitivity (IS: 35 J) and enhanced reaction activity with aluminium powders in melt-cast explosive formulations.

AB - A trifluoropropyl functionalized energetic compound, viz. 3,5-dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine (TFDNPA), was designed and synthesized, which exhibited potential for TNT replacement as an energetic melt-castable carrier in aluminized explosive formulation due to excellent thermal properties (Tm: 100 °C and Td: 261 °C), good detonation performance (D: 7330 m s−1 and P: 23.3 GPa), low impact sensitivity (IS: 35 J) and enhanced reaction activity with aluminium powders in melt-cast explosive formulations.

UR - https://www.scopus.com/pages/publications/85210998855

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DO - 10.1039/d4ce01036a

M3 - 文章

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SN - 1466-8033

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IS - 1

ER -

3,5-Dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine as an insensitive and thermostable energetic melt-castable material

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