1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions

Xiaoju Liu; Guoyu Ren; Xiangrong Ma; Yulin Xiang; Liguo Gao; Xiaoyan Ma

doi:10.1134/S1070427217120187

1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co²⁺ and Cu²⁺ Ions

Xiaoju Liu
, Guoyu Ren
, Xiangrong Ma
, Yulin Xiang
, Liguo Gao
, Xiaoyan Ma

School of Chemistry and Chemical Engineering

Yulin University

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co²⁺ and Cu²⁺ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co²⁺, Cu²⁺, Zn²⁺, and Ni²⁺ in water) and the binding constants for Co²⁺ and Cu²⁺ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.

Original language	English
Pages (from-to)	2016-2018
Number of pages	3
Journal	Russian Journal of Applied Chemistry
Volume	90
Issue number	12
DOIs	https://doi.org/10.1134/S1070427217120187
State	Published - 1 Dec 2017

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title = "1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions",

abstract = "An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.",

author = "Xiaoju Liu and Guoyu Ren and Xiangrong Ma and Yulin Xiang and Liguo Gao and Xiaoyan Ma",

note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",

year = "2017",

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doi = "10.1134/S1070427217120187",

language = "英语",

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TY - JOUR

T1 - 1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane

T2 - Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions

AU - Liu, Xiaoju

AU - Ren, Guoyu

AU - Ma, Xiangrong

AU - Xiang, Yulin

AU - Gao, Liguo

AU - Ma, Xiaoyan

PY - 2017/12/1

Y1 - 2017/12/1

N2 - An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.

AB - An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.

UR - https://www.scopus.com/pages/publications/85045279448

U2 - 10.1134/S1070427217120187

DO - 10.1134/S1070427217120187

M3 - 文章

AN - SCOPUS:85045279448

SN - 1070-4272

VL - 90

SP - 2016

EP - 2018

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

IS - 12

ER -

1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane: Synthesis, Structure and Recognition Properties for Co²⁺ and Cu²⁺ Ions

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