一例具有高效 C2H2/CO2 分离性能的柱层式多孔配位聚合物

Rong Yang; Xue Zhang; Jinbo Wang; Lu Cheng; Yu Wang; Kaijie Chen

doi:10.16026/j.cnki.iea.2023060501

一例具有高效 C₂H₂/CO₂ 分离性能的柱层式多孔配位聚合物

Translated title of the contribution: A Pillared-Layer Porous Coordination Polymer for Efficient C₂H₂/CO₂ Separation

Rong Yang
, Xue Zhang
, Jinbo Wang
, Lu Cheng
, Yu Wang
, Kaijie Chen

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The separation and purification of C₂H₂ from C₂H₂/CO₂ mixture is of great challenging due to their similar physical and chemical properties. In this study, a pillared-layer ultramicroporous coordination polymer with polar pore surface bearing with N/O atoms Co-datz-mipa (Hdatz=3, 5-diamino-1, 2, 4-triazole; H₂mipa=5-methyl-isophthalic acid) was used as an efficient adsorbent for C₂H₂/CO₂ separation. Polar N/O atoms can form specific recognition with C₂H₂. Adsorption isotherms and dynamic breakthrough curves show that Co-datz-mipa can adsorb C₂H₂ selectively from CO₂.

Translated title of the contribution	A Pillared-Layer Porous Coordination Polymer for Efficient C₂H₂/CO₂ Separation
Original language	Chinese (Traditional)
Pages (from-to)	501-511
Number of pages	11
Journal	Lizi Jiaohuan Yu Xifu/Ion Exchange and Adsorption
Volume	39
Issue number	6
DOIs	https://doi.org/10.16026/j.cnki.iea.2023060501
State	Published - 20 Dec 2023

Access to Document

10.16026/j.cnki.iea.2023060501

Cite this

@article{d1ba9b19c8624bb0a44e67ffaee94c62,

title = "一例具有高效 C2H2/CO2 分离性能的柱层式多孔配位聚合物",

abstract = "The separation and purification of C2H2 from C2H2/CO2 mixture is of great challenging due to their similar physical and chemical properties. In this study, a pillared-layer ultramicroporous coordination polymer with polar pore surface bearing with N/O atoms Co-datz-mipa (Hdatz=3, 5-diamino-1, 2, 4-triazole; H2mipa=5-methyl-isophthalic acid) was used as an efficient adsorbent for C2H2/CO2 separation. Polar N/O atoms can form specific recognition with C2H2. Adsorption isotherms and dynamic breakthrough curves show that Co-datz-mipa can adsorb C2H2 selectively from CO2.",

keywords = "Acetylene purification, Adsorptive separation, Pillared-layer structure, Porous coordination polymer, Ultramicropore",

author = "Rong Yang and Xue Zhang and Jinbo Wang and Lu Cheng and Yu Wang and Kaijie Chen",

year = "2023",

month = dec,

day = "20",

doi = "10.16026/j.cnki.iea.2023060501",

language = "繁体中文",

volume = "39",

pages = "501--511",

journal = "Lizi Jiaohuan Yu Xifu/Ion Exchange and Adsorption",

issn = "1001-5493",

publisher = "Tianjin Nankai Daxue",

number = "6",

}

TY - JOUR

T1 - 一例具有高效 C2H2/CO2 分离性能的柱层式多孔配位聚合物

AU - Yang, Rong

AU - Zhang, Xue

AU - Wang, Jinbo

AU - Cheng, Lu

AU - Wang, Yu

AU - Chen, Kaijie

PY - 2023/12/20

Y1 - 2023/12/20

N2 - The separation and purification of C2H2 from C2H2/CO2 mixture is of great challenging due to their similar physical and chemical properties. In this study, a pillared-layer ultramicroporous coordination polymer with polar pore surface bearing with N/O atoms Co-datz-mipa (Hdatz=3, 5-diamino-1, 2, 4-triazole; H2mipa=5-methyl-isophthalic acid) was used as an efficient adsorbent for C2H2/CO2 separation. Polar N/O atoms can form specific recognition with C2H2. Adsorption isotherms and dynamic breakthrough curves show that Co-datz-mipa can adsorb C2H2 selectively from CO2.

AB - The separation and purification of C2H2 from C2H2/CO2 mixture is of great challenging due to their similar physical and chemical properties. In this study, a pillared-layer ultramicroporous coordination polymer with polar pore surface bearing with N/O atoms Co-datz-mipa (Hdatz=3, 5-diamino-1, 2, 4-triazole; H2mipa=5-methyl-isophthalic acid) was used as an efficient adsorbent for C2H2/CO2 separation. Polar N/O atoms can form specific recognition with C2H2. Adsorption isotherms and dynamic breakthrough curves show that Co-datz-mipa can adsorb C2H2 selectively from CO2.

KW - Acetylene purification

KW - Adsorptive separation

KW - Pillared-layer structure

KW - Porous coordination polymer

KW - Ultramicropore

UR - https://www.scopus.com/pages/publications/85207281438

U2 - 10.16026/j.cnki.iea.2023060501

DO - 10.16026/j.cnki.iea.2023060501

M3 - 文章

AN - SCOPUS:85207281438

SN - 1001-5493

VL - 39

SP - 501

EP - 511

JO - Lizi Jiaohuan Yu Xifu/Ion Exchange and Adsorption

JF - Lizi Jiaohuan Yu Xifu/Ion Exchange and Adsorption

IS - 6

ER -

一例具有高效 C₂H₂/CO₂ 分离性能的柱层式多孔配位聚合物

Abstract

Access to Document

Other files and links

Fingerprint

Cite this